The Reaction of Iron Pentacarbonyl with Acetylacetone
โ Scribed by Fitch, J. W.; Lagowski, J. J.
- Book ID
- 126873088
- Publisher
- American Chemical Society
- Year
- 1965
- Tongue
- English
- Weight
- 136 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0020-1669
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
This communication reports a simple, rapid and convenient means of converting sulfonyl chlorides I to thiolsulfonate esters II using a 1:l mixture of iron pentacarbonyl and boron trifluoride ether-ate in N,N-dimethylacetamide (DMAC) or tetramethylurea (TMU). A typical procedure follows. BFx.(C7H5)7
In 1959, Hieber and Lipp' reported briefly the deoxygenatlon of pyridine N-oxide with iron pentacarbonyl. In view of the highly polar N-C bond of Nnitrosamines (which can formally be viewed as N-nltrene N-oxides), the action of iron pentacarbonyl of N-nltrosamlnes was considered as a possible route