✦ LIBER ✦

On the photodissociation of nitromethane at 266 nm

✍ Scribed by H. S. Kwok; G. Z. He; R. K. Sparks; Y. T. Lee

Publisher: John Wiley and Sons
Year: 1981
Tongue: English
Weight: 352 KB
Volume: 13
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550131103

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✦ Synopsis

Abstract

In a crossed laser–molecular beam study of nitromethane it was found that the excitation of nitromethane at 266 nm did not yield dissociation products under collision‐free conditions. When a small cluster of nitromethane was excited at the same frequency, the product was seen only at energies and masses consistent with the rupture of the van der Waals bond by vibrational predissociation of the excited state.

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