The rotational distribution of CN( B "C, v=O) dissociated from ICN at I93 nm is well represented by a thermal rotational distribution for T= 250 K, giving an average energy of I75 cm-'. The energy of the highest rotational state detected (N= 28) suggests that some or all of the molecules dissociated
Rotational distribution of CN from the 266 nm photodissociation of ICN
✍ Scribed by W. Krieger; J. Häger; J. Pfab
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 393 KB
- Volume
- 85
- Category
- Article
- ISSN
- 0009-2614
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## Abstract In a crossed laser–molecular beam study of nitromethane it was found that the excitation of nitromethane at 266 nm did not yield dissociation products under collision‐free conditions. When a small cluster of nitromethane was excited at the same frequency, the product was seen only at en
Potential energy surfaces of low-lying excited states of ICN have been calculated for linear and bent dissociation using the ab initio spin-orbit CI method with the effective spin-orbit Hamiltoman. Contrary to popular belief, all the relevant excited surfaces are bent in the Franck-Condon region and