✦ LIBER ✦

Picosecond laser study of the collisionless photodissociation of dimethylnitramine at 266 nm

✍ Scribed by Jean-Claude Mialocq; John C. Stephenson

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 389 KB
Volume: 123
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)80028-8

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✦ Synopsis

We report a picosecond pump-probe study of the UV photolysis of gaseous dimethylnitramine.

After photolysis by picosecond laser pulses at 266 nm, efficient monophotonic collision-free photodissociation occurs within 6 ps. NO* fragments are formed in the ground electronic state and in a fluorescent excited state: the quantum yields for both of these channels are estimated.

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