✦ LIBER ✦

Photodissociation of D2O in the second continuum by two-photon absorption at 266 nm

✍ Scribed by R.G. Briggs; J.B. Halpern; G. Hancock; N. Shafizadeh; J. Rostas; J.L. Lemaire; F. Rostas

Publisher: Elsevier Science
Year: 1989
Tongue: English
Weight: 406 KB
Volume: 156
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(89)87109-x

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✦ Synopsis

The rotational population distribution of OD*(A 'Z* ) fragments produced by two-photon photodissociation of D20 at 266 nm has been determined from an analysis of the A *x+-X 'I-I fluorescence. The distribution obtained seems to confirm the existence of long-lived trajectories when the dissociation of Hz0 or D1O is initiated with a small energy excess above the threshold for production of excited OH (OD) fragments.

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