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The photodissociation of iodine monochloride at 235 nm

✍ Scribed by Leon J. Rogers; Michael N.R. Ashfold; Yutaka Matsumi; Masahiro Kawasaki; Benjamin J. Whitaker

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
333 KB
Volume
258
Category
Article
ISSN
0009-2614

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✦ Synopsis

The photodissociation of iodine monochloride following excitation at 235 nm, within its second absorption band, has been investigated further using ion imaging methods to monitor the Cl(2P~/2 ) and C1 * (2P~/2) atomic products. The angular distributions of these products are found to be characterised by anisotropy parameters, /3 = 1.8 _+ 0.2 and -1.0 _ 0.1 for the Cl and CI * products, respectively, whilst the measured Cl/C1 * translational energies indicate the involvement of the two product channels: IC1 + h~,(A = 235 nm) ~ Cl + I * (2P~/2) and Cl* + I(2P3Β°/2).

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