## Abstract The title reaction, which is spinβforbidden for N~2~(X^1^β) + NO(X^2^Ξ ) production, has been studied from 960 to 1130 K in a highβtemperature photochemistry reactor. No reaction could be observed, indicating __k__ < 1 Γ 10^β15^ cm^3^ molecule^β1^ s^β1^. It is concluded that there is no
On the kinetics of the reaction of Zn(1S) with N2O
β Scribed by George A. Raiche; Joseph J. Belbruno
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 547 KB
- Volume
- 134
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
O ( l D ) , produced from the photolysis ofN,O at 2139 A, reacts with N,O in accord with: We have used the method of chemical difference to obtain an accurate measure of k,/k, = 0.59 f 0.01. Furthermore, the quantum yield of production of O ( , P ) , either on direct photolysis or on deactivation o
The kinetics of the reaction of 0 atoms with NO2 was investigated in the temperature range 199-357 K. The value of the rate constant can be expressed by k, = (5.21 kO.50) x lo-'\* exp [(202\*27)lT] cm3 s-' (3~ error). At temperatures below 230 K, the formation of equilibrium concentrations of N204 a
&te coefficients for the reaction of Cl-I,0 ~th NO 2 were measured over the temperature range 21-O-473 K and over tie pressure range 0 6-4 0 Torr using a flow reactor apparatus uqth laser-Induced fluorescence (LIF) detection of CH,O The results were fitted LO extract recombmatlon and &sproporuonauon