The reaction of CF3 radicals with Ha0 (D20) has been studied over the range of 533-723 K using the photolysis and the pyrolysis of CFJ as the free radical source. Arrhenius pa- rameters for the reactions where X = H or D, relative to CF:j radical recombination are given by log kHlkf'2 = (5.12 f 0.1
Reaction of O(1D) with N2O
β Scribed by Raymond I. Greenberg; Julian Heicklen
- Publisher
- John Wiley and Sons
- Year
- 1970
- Tongue
- English
- Weight
- 207 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0538-8066
No coin nor oath required. For personal study only.
β¦ Synopsis
O ( l D ) , produced from the photolysis ofN,O at 2139 A, reacts with N,O in accord with:
We have used the method of chemical difference to obtain an accurate measure of k,/k, = 0.59 f 0.01. Furthermore, the quantum yield of production of O ( , P ) , either on direct photolysis or on deactivation of O(l0) by N,O, is less than 0.02 and probably zero.
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