H2 formation in the reaction of O(1D) with CH4
โ Scribed by R. K. M. Jayanty; R. Simonaitis; Julian Heicklen
- Publisher
- John Wiley and Sons
- Year
- 1976
- Tongue
- English
- Weight
- 163 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0538-8066
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โฆ Synopsis
Abstract
The reaction of O(^1^D) with CH~4~ was studied to determine the efficiency of H~2~ production in a direct process, and it was found to be 0.11 ยฑ 0.02. Thus the two channels which account for all of the reaction between O(^1^D) and CH~4~ in the gas phase are
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๐ SIMILAR VOLUMES
Results obtained from the photolysis of ketene with acetylene strongly support the formation of C,H, radicals in the title reaction. Stationary state studies are interpreted in terms of the reaction C,H: 5 C,H, + H with a rate constant (log8 s '1 which is compared to RRKM predictions. In pulsed lase
O ( l D ) , produced from the photolysis ofN,O at 2139 A, reacts with N,O in accord with: We have used the method of chemical difference to obtain an accurate measure of k,/k, = 0.59 f 0.01. Furthermore, the quantum yield of production of O ( , P ) , either on direct photolysis or on deactivation o
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