The kinetics of the gas-phase reactions of the OH radical with (C,H,O),PO and (CH30)2P(S)C1 and of the reactions of NO, radicals and O3 with (CH,O),P(S)Cl have been studied at room temperature. Using a relative rate technique, the rate constants determined for the reactions of the OH radical with (C
The reaction of O(3P) with H2O2
β Scribed by John M. Roscoe
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- English
- Weight
- 399 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0538-8066
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β¦ Synopsis
The rate constant for the reaction of O(") with H202 was measured as a function of temperature and the [H202]0/[0]0 ratio. The numerical solution of the appropriate rate equations was used to arrive a t a mechanism which adequately describes our results and the rather divergent data in the literature. A recommended expression for the temperature dependence of the absolute rate constant is presented from consideration of the available experimental data.
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The reaction of CF3 radicals with Ha0 (D20) has been studied over the range of 533-723 K using the photolysis and the pyrolysis of CFJ as the free radical source. Arrhenius pa- rameters for the reactions where X = H or D, relative to CF:j radical recombination are given by log kHlkf'2 = (5.12 f 0.1
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