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The N(4S) + N2O(X̃1∑) reaction

✍ Scribed by Abel Fernandez; Arthur Fontijn

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
55 KB
Volume
33
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

The title reaction, which is spin‐forbidden for N~2~(X^1^∑) + NO(X^2^Π) production, has been studied from 960 to 1130 K in a high‐temperature photochemistry reactor. No reaction could be observed, indicating k < 1 × 10^−15^ cm^3^ molecule^−1^ s^−1^. It is concluded that there is no significant contribution from the spin‐allowed exothermic path leading to N~2~(X^1^∑) + NO(a^4^Π). © 2001 John Wiley & Sons, Inc. Int J Chem Kinet 33: 387–389, 2001

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