## Abstract Relative rate constants for the reaction of OH radicals with a series of __n__โalkanes have been determined at 299 ยฑ 2 K, using methyl nitrite photolysis in air as a source of OH radicals. Using a rate constant for the reaction of OH radicals with __n__โbutane of 2.58 ร 10^โ12^ cm^3^ mo
Kinetics of the reactions of OH radicals with CO and N2O
โ Scribed by R. Atkinson; R.A. Perry; J.N. Pitts Jr.
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 458 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
The reactions of N,O with NO and OH radicals have been studied using ab initio molecular orbital theory The energetics and molecular parameters, calculated by the modified Gaussian-2 method ( G 2 M ) . have been used to compute the reaction rate constants on the basis of the TST and RRKM theories Th
The rate constants for the reaction of CN with NzO and COz have been measured by the laser dissociation/laser-induced fluorescence (two-laser pump-probe) technique at temperatures between 300 and 740 K. The rate of CN + NzO was measurable above 500 K, with a least-squares averaged rate constant, k =
Rate constants for the reactions of 0 3 and OH radicals with furan and thiophene have been determined at 298 f 2 K. The rate constants obtained for the 0 3 reactions were (2.42 f 0.28) X 1O-lS cm3/molec.s for furan and <6 X cm3/molec-s for thiophene. The rate constants for the OH radical reactions,
The rate constant for the reaction of OH radicals with pinonaldehyde has been measured at 293 ฯฎ 6 K using the relative rate method in the laboratory in Wuppertal (Germany) using photolytic sources for the production of OH radicals and in the EUPHORE smog chamber facility in Valencia (Spain) using th
Absolute rate constants for the reaction OH + SO2 + N2 have been determined in the gas phase, at 297 K, in the pressure range SO-760 Torr. OH radicals were grnerated by flash photolysis of NzO/Hz mixtures and were monitored by time-resolved resonance absorption. The second-order rate constant $I was