Reaction of cupferron [NH 4 L, L = PhN(O)NO -] with tin(IV), complex 2. The tin centers are heptacoordinated in a pentagonal bipyramidal geometry in the dimeric complex 3. diphenyltin(IV) and dimethyltin(IV) halides yields the cupferronato complexes SnL 4 (1), Ph 2 SnL 2 (2) and These complexes inco
Kinetic study of the reactions Sn+N2O→SnO+N2
✍ Scribed by J.R. Wiesenfeld; M.J. Yuen
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 575 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0009-2614
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📜 SIMILAR VOLUMES
Product (NzD? angular and velocity distributions were experimentally determined over a relative energy range of 1-16 eV. At the lowest energy. the reaction was conclusively shown to proceed by an impukive mode (stripping).
The rate constants for the reaction of CN with NzO and COz have been measured by the laser dissociation/laser-induced fluorescence (two-laser pump-probe) technique at temperatures between 300 and 740 K. The rate of CN + NzO was measurable above 500 K, with a least-squares averaged rate constant, k =
Data are presented which strongly suggest that stabilisation of the eacrted intermediate o\lz)\* complex in the reaction (1) Nt + 2Nz (rate coefficient kl) occurs via N2 switching whereas for (2) Nt + Nz + He (rate coefticient k,) it occursvia superelastic He collisions. This explains the differing
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