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Further studies of the N2+ + N2 → N4+ association reaction

✍ Scribed by D. Smith; N.G. Adams; E. Alge

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
395 KB
Volume
105
Category
Article
ISSN
0009-2614

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✦ Synopsis

Data are presented which strongly suggest that stabilisation of the eacrted intermediate o\lz)* complex in the reaction (1) Nt + 2Nz (rate coefficient kl) occurs via N2 switching whereas for (2) Nt + Nz + He (rate coefticient k,) it occursvia superelastic He collisions. This explains the differing temperature variations of k, and k, previously obttined for these reactions. Drift tube data are also presented which show how k, varies with N;/N* centre-of-mass energy as compared with thermal energy.

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