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Kinetics of the reaction of CH3O with NO2

✍ Scribed by J.A. McCaulley; S.M. Anderson; J.B. Jeffries; F. Kaufman

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 638 KB
Volume: 115
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)80675-8

No coin nor oath required. For personal study only.

✦ Synopsis

&te coefficients for the reaction of Cl-I,0 ~th NO 2 were measured over the temperature range 21-O-473 K and over tie pressure range 0 6-4 0 Torr using a flow reactor apparatus uqth laser-Induced fluorescence (LIF) detection of CH,O The results were fitted LO extract recombmatlon and &sproporuonauon rate constants Combmed with prewous mdlrect studies at h@er pressure. they suggest that the reacuon proceeds not through a smgle complex but by separate paths, with dlspropon:onatlon occumng by &rect H-atom abstracuon

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