&te coefficients for the reaction of Cl-I,0 ~th NO 2 were measured over the temperature range 21-O-473 K and over tie pressure range 0 6-4 0 Torr using a flow reactor apparatus uqth laser-Induced fluorescence (LIF) detection of CH,O The results were fitted LO extract recombmatlon and &sproporuonauon
Kinetic spectroscopy study of the reaction of CH3O2 with NO
โ Scribed by Hiroyuki Adachi; Norman Basco
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 314 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Pulse radiolysis was used to study the kinetics of the reactions of CH 3 C(O)CH 2 O 2 radicals with NO and NO 2 at By monitoring the rate of formation and decay of NO 2 295 K. using its absorption at the rate constants 400 and 450 nm k(CH C(O)CH O ฯฉ NO) ฯญ (8 ฯฎ 3 2 2 and were de-ฯช12 ฯช12 3 ฯช1 ฯช1 2) ฯซ
The overall rate constant for the reaction between ethylperoxy radicals and nitric oxide has been directly measured by flash photolysis and kinetic spectroscopy. At room temperature the rate constant k 7 = (1.6\* 0.1) X 10' litremole-' F' has been assigned to the reaction C2H502 + NO + CzHsO + NO\*\
The order of the combination reaction CH3 4 O2 has been shown to lie bet;Keen two and three throughout the pressure range from 30 to 380 torr at 22 rE ZยฐC, and the limiting value of the second order rate constant at high pressure is (2.7i0.2) X 108 Like moIe'I se& \_