✦ LIBER ✦

Kinetic spectroscopy study of the reaction of C2H5O2 with NO

✍ Scribed by Hiroyuki Adachi; Norman Basco

Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 303 KB
Volume: 64
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(79)80215-8

No coin nor oath required. For personal study only.

✦ Synopsis

The overall rate constant for the reaction between ethylperoxy radicals and nitric oxide has been directly measured by flash photolysis and kinetic spectroscopy. At room temperature the rate constant k 7 = (1.6* 0.1) X 10' litremole-' F' has been assigned to the reaction C2H502 + NO + CzHsO + NO*_

📜 SIMILAR VOLUMES

Kinetic spectroscopy study of the reacti

Kinetic spectroscopy study of the reaction of CH3O2 with NO

✍ Hiroyuki Adachi; Norman Basco 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 314 KB

Kinetics of the reaction of C2H5O2 with

Kinetics of the reaction of C2H5O2 with NO at 295 K

✍ I. C. Plumb; K. R. Ryan; J. R. Steven; M. F. R. Mulcahy 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 593 KB

The reaction of CzH502 with NO in helium carrier gas at 295 K with [He] = 1.6 X 1017 cm-3 has been studied using a gas flow reactor sampled by a mass spectrometer. Because no parent molecular ion or suitable fragment ion produced by CzH502 could be detected, the reaction was followed by measuring th

Temperature-dependent kinetics studies o

Temperature-dependent kinetics studies of the reactions of C2H5O2 and n-C3H7O2 radicals with NO

✍ Jürg Eberhard; Carleton J. Howard 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 571 KB

The rate coefficients for the gas-phase reactions of C,H,O;, and n-C3H,0, radicals with NO have been measured over the temperature range of (201 -403) K using chemical ionization mass spectrometric detection of the peroxy radical. The alkyl peroxy radicals were generated by reacting alkyl radicals w

Kinetic studies of the reaction of C2H5

Kinetic studies of the reaction of C2H5 with O2 at 295 K

✍ I. C. Plumb; K. R. Ryan 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 English ⚖ 885 KB

The reaction between CzH5 and 0 2 a t 295 K has been studied with a flow reactor sampled by a mass spectrometer. With helium as the carrier gas the rate coefficient was found to increase from (1.2 f 0.3) X cm3/s as [He] was increased from 2 X 10I6 to 3.4 X 1017 The importance of to (3.6 f 0.9) has

Kinetic study of reactions of C2H5O2 wit

Kinetic study of reactions of C2H5O2 with NO at 298 K and 0.55 – 2 torr

✍ V. Daële; A. Ray; I. Vassalli; G. Poulet; G. Le Bras 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 791 KB

The kinetics of CzH50 and CzH502 radicals with NO have been studied at 298 K using the discharge flow technique coupled to laser induced fluorescence (LIF) and mass spectrometry analysis. The temporal profiles of CzH5O were monitored by LIF. The rate constant for CzH5O + NO -Products (21, measured i

Theoretical and kinetic study of the H +

Theoretical and kinetic study of the H + C2H5CN reaction

✍ Jingyu Sun; Yizhen Tang; Hao Sun; Xiujuan Jia; Xiumei Pan; Rongshun Wang 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 374 KB 👁 2 views

## Abstract The reaction of H radical with C~2~H~5~CN has been studied using various quantum chemistry methods. The geometries were optimized at the B3LYP/6‐311+G(d,p) and B3LYP/6‐311++G(2d,2p) levels. The single‐point energies were calculated using G3 and BMC‐CCSD methods based on B3LYP/6‐311++G(2