Pulse radiolysis was used to study the kinetics of the reactions of CH 3 C(O)CH 2 O 2 radicals with NO and NO 2 at By monitoring the rate of formation and decay of NO 2 295 K. using its absorption at the rate constants 400 and 450 nm k(CH C(O)CH O ϩ NO) ϭ (8 Ϯ 3 2 2 and were de-Ϫ12 Ϫ12 3 Ϫ1 Ϫ1 2) ϫ
Flash photolysis kinetic study of the equilibrium CH3O2+NO2⇌CH3O2NO2
✍ Scribed by Isabelle Bridier; Robert Lesclaux; Bernard Veyret
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 274 KB
- Volume
- 191
- Category
- Article
- ISSN
- 0009-2614
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Rate constants for the reactions of OH radicals and Cl atoms with CH,CH,NO>, CH,CH,CH,NO,, CH3CH2CH2CHzN02, and CH,CH2CH2CH,CH2N02 have been determined at 295+3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis co
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