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New allyl group acceptors for palladium catalyzed removal of allylic protections and transacylation of allyl carbamates

✍ Scribed by Michèle Dessolin; Marie-George Guillerez; Nathalie Thieriet; François Guibé; Albert Loffet

Book ID
103402728
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
182 KB
Volume
36
Category
Article
ISSN
0040-4039

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Oximes are protected by O-ally1 ether formation, and their palladium-catalyzed deallylation using triethylammonium formate as a reductant proceeds smoothly in boiling ethanol under mild conditions offering a good protective method for oximes. Oxime formation offers a good protection for carbonyl gr