✦ LIBER ✦
O-allyl ether as a new protective group for oximes and its palladium-catalyzed deprotection
✍ Scribed by Toshiro Yamada; Kuniaki Goto; Yasuhiro Mitsuda; Jiro Tsuji
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- French
- Weight
- 242 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Oximes are protected by O-ally1 ether formation, and their palladium-catalyzed deallylation using triethylammonium formate as a reductant proceeds smoothly in boiling ethanol under mild conditions offering a good protective method for oximes.
Oxime formation offers a good protection for carbonyl groups.') However,