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Homogeneous, palladium(0)-catalyzed exchange deprotection of allylic esters, carbonates and carbamates

✍ Scribed by Jeffrey, Paul D.; McCombie, Stuart W.

Book ID
120277851
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
610 KB
Volume
47
Category
Article
ISSN
0022-3263

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4-Quinolylmethyl (4-QUI) esters of carboxylic acids and 1-naphthyimethyi (1-NAP) esters of carbonic and carbamic acids are reduced by palladium-catalyzed hydrogenolysis by formate anion. The reaction conditions are compatible with the presence of a benzyl ester and of an alkene double bond.