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Palladium-catalyzed reaction of allyl carbamates; allylation of carbonucleophiles, and protection-deprotection of amines

✍ Scribed by Ichiro Minami; Yukihiro Ohashi; Isao Shimizu; Jiro Tsuji

Book ID
108382565
Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
232 KB
Volume
26
Category
Article
ISSN
0040-4039

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Synthesis of protected allylic amines vi
Synthesis of protected allylic amines via palladium(0)-catalyzed amination of allylic acetates
✍ Nilantha S. Sirisoma; Patrick M. Woster πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 188 KB

Synthesis of potential antiparisitic 5'-aminonucloesides such as 10 could not be accomplished using standard amination procedures. Palladium(0)-catalyzed amination of cyclic allylic acetates with benzylamine or phthalimide gave the corresponding protected amines. This method was then extended to the