Allylic carbonates. Efficient allylating agents of carbonucleophiles in palladium-catalyzed reactions under neutral conditions
โ Scribed by Tsuji, Jiro; Shimizu, Isao; Minami, Ichiro; Ohashi, Yukihiro; Sugiura, Teruo; Takahashi, Kazuhiko
- Book ID
- 115468515
- Publisher
- American Chemical Society
- Year
- 1985
- Tongue
- English
- Weight
- 857 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
Palladium catalyzed decarboxylative allylation of active methylene compounds proceeded under mild neutral conditions using allylic carbonates, which are much more reactive than allylic acetates or phenoxides used commonly in the reaction.
Treatment of alkyl allylcarbonates derived from various alcohols with a palladium catalyst in MeCN affords ketones and aldehydes in high yields. This new method of oxidation of alcohols can be applied to various alcohols except simple primary alcohols.