Allyation of carbonucleophiles with allylic carbonates under neutral conditions catalyzed by rhodium complexes
β Scribed by Jiro Tsuji; Ichiro Minami; Isao Shimizu
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 221 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
Palladium catalyzed decarboxylative allylation of active methylene compounds proceeded under mild neutral conditions using allylic carbonates, which are much more reactive than allylic acetates or phenoxides used commonly in the reaction.
Treatment of alkyl allylcarbonates derived from various alcohols with a palladium catalyst in MeCN affords ketones and aldehydes in high yields. This new method of oxidation of alcohols can be applied to various alcohols except simple primary alcohols.
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