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Efficient Redox Isomerization of Allylic Alcohols under Mild Conditions Catalyzed by Arene—Ruthenium(II) Complexes.

✍ Scribed by Pascale Crochet; Mariano A. Fernandez-Zumel; Jose Gimeno; Marcus Scheele

Publisher
John Wiley and Sons
Year
2007
Weight
30 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

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## Abstract The water‐soluble complexes [RuCl~2~(η^6^‐__p__‐cymene){__κ__‐(__P__)‐PPh~3n~(OCH~2~CH~2~NMe~3~)~n~}][SbF~6~]~n~ [n=1 (4a), 2 (4b) or 3 (4c)] have been prepared from the neutral precursors [RuCl~2~(η^6^‐__p__‐cymene){__κ__‐(__P__)‐PPh~3‐n~(OCH~2~CH~2~NMe~2~)~n~}] [n=1 (2a), 2 (2b) or 3