Catalytic Isomerization of Allylic Alcohols by (η6-p-Cymene)-Ruthenium(II) Complexes in Organic and Aqueous Media: New Recyclable and Highly Efficient Catalysts in Water Containing Ammonium-Functionalized Ligands.

Catalytic Isomerization of Allylic Alcoh

Catalytic Isomerization of Allylic Alcohols by (η6-p-Cymene)- Ruthenium(II) Complexes in Organic and Aqueous Media: New Recyclable and Highly Efficient Catalysts in Water Containing Ammonium-Functionalized Ligands

✍ Pascale Crochet; Josefina Díez; Mariano A. Fernández-Zúmel; José Gimeno 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 133 KB 👁 1 views

## Abstract The water‐soluble complexes [RuCl~2~(η^6^‐__p__‐cymene){__κ__‐(__P__)‐PPh~3n~(OCH~2~CH~2~NMe~3~)~n~}][SbF~6~]~n~ [n=1 (4a), 2 (4b) or 3 (4c)] have been prepared from the neutral precursors [RuCl~2~(η^6^‐__p__‐cymene){__κ__‐(__P__)‐PPh~3‐n~(OCH~2~CH~2~NMe~2~)~n~}] [n=1 (2a), 2 (2b) or 3