๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Palladium-catalyzed oxidation of alcohols via their allyl carbonates under neutral conditions

โœ Scribed by Jiro Tsuji; Ichiro Minami; Isao Shimizu

Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
101 KB
Volume
25
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

โœฆ Synopsis

Treatment of alkyl allylcarbonates derived from various alcohols with a palladium catalyst in MeCN affords ketones and aldehydes in high yields.

This new method of oxidation of alcohols can be applied to various alcohols except simple primary alcohols.

๐Ÿ“œ SIMILAR VOLUMES

Facile Palladium catalyzed decarboxylati
Facile Palladium catalyzed decarboxylative allylation of active methylene compounds under neutral conditions using allylic carbonates
โœ Jiro Tsuji; Isao Shimizu; Ichiro Minami; Yukihiro Ohashi ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 219 KB

Palladium catalyzed decarboxylative allylation of active methylene compounds proceeded under mild neutral conditions using allylic carbonates, which are much more reactive than allylic acetates or phenoxides used commonly in the reaction.

Allyl ethyl carbonate/palladium (0), a n
Allyl ethyl carbonate/palladium (0), a new system for the one step conversion of alcohols into allyl ethers under neutral conditions
โœ R. Lakhmiri; P. Lhoste; D. Sinou ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 212 KB

Alcohols are converted in a one-step procedure into ally1 ethers under neutral conditions, using ally1 ethyl carbonate in the presence of a catalytic amount of palladium (0). Anomeric hydroxyls are selectively allylated in the presence of other hydroxyl groups. Ally1 groups have been found to be of