✦ LIBER ✦
The allyloxycarbonyl group for alcohol protection: quantitative removal or transformation into allyl protecting group via π-allyl complexes of palladium
✍ Scribed by F. Guibe; Y.Saint M'leux
- Book ID
- 104234299
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 236 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
In the presence of Pd catalysts and under mild, essentially nonbasic conditions, the ally1oxycarbonyl.derivative.s of alcohols may be either converted into the corresponding ally1 ethers or hydrogenolysed (Bu3SnH) back to the starting alcohol.