Asymmetric catalysis / Allylic alkylation / 1-Methyl-5-(1Π-methylpent-2Π-ynyl)barbituric acid / Palladium catalysts / Chiral phosphane imine ligands / Methohexital / Anesthetic dose Allylation of 1-methyl-5-(1Π-methylpent-2Π-ynyl)barbituric Chiral phosphane imine ligands are a successful class of c
Removal of Allyl groups by Formic Acid Catalyzed by (Triphenylphosphane)palladium
β Scribed by Dr. H. Hey; Dr. H.-J. Arpe
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- English
- Weight
- 184 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0044-8249
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π SIMILAR VOLUMES
for their generous supply of ligands 24 and 10, 14, and 15, respectively. We are indebted to Corrado Sangermani and Gloria Borin for their synthetic expertise and contributions. Special thanks go to Maurizio Franzini for his advice. This work was supported by the University of Pavia (Progetto Giovan
The 1,2-asymmetric induction in the formation of new Differences in stereoselectivity for varying substrates can be understood when modified Taft parameters, the homo-E s quaternary centers by palladium-catalyzed allylation of substituted cyanoacetates 1a-c was controlled by using 2,9-values, are co