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Mild Method for the Synthesis of Thiazolines from Secondary and Tertiary Amides

✍ Scribed by Charette, André B.; Chua, Peter

Book ID
120220293
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
46 KB
Volume
63
Category
Article
ISSN
0022-3263

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📜 SIMILAR VOLUMES

ChemInform Abstract: Mild Method for the
ChemInform Abstract: Mild Method for the Synthesis of Thiazolines from Secondary and Tertiary Amides.
✍ A. B. CHARETTE; P. CHUA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 2 views

Mild Method for the Synthesis of Thiazolines from Secondary and Tertiary Amides. -Base-promoted treatment of amides [cf. (I)] with triflic anhydride generates an iminium or imino triflate which reacts with an aminothiol directly to biologically interesting thiazolines. When optically pure cysteine

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The reduction of amides with lithium aluminum hydride, aluminum hydride, lithium trimethoxyaluminum hydride, and diborane to the corresponding amines is well known (1).

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1998 amide formation, amide hydrolysis amide formation, amide hydrolysis O 0320 23 -069 A New Mild Method for the Cleavage of the Amide Bond: Conversion of Secondary and Tertiary Amides to Esters. -A variety of secondary and tertiary amides (I) (21 examples) is efficiently converted to the correspon

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Samarium-mediated facile method for the formation of amide bonds by the reaction of acyl chlorides and amines is described. The reaction afforded high yields of the desired amides under mild and neutral conditions.