The anodic films formed on tantalum in many non-aqueous solutions have been found to consist of two layers. Next to the metal there is a layer of Ta206 with the same characteristics as that of films formed in aqueous electrolytes, while between the TaeOb film and the solution there is a layer which
Migration of incorporated phosphorus in the anodic oxide film formation of tantalum
โ Scribed by Fumihiro Arifuku; Hiroshi Yoneyama; Hideo Tamura
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 337 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0013-4686
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โฆ Synopsis
Almbxct -The mobility of phosphorus incorporated as a mass marker into tantalum anodic oxide films was investigetcd by mtans of ion microprobe mass analysis. If the transport number of tantalum ions for the film formation is ~ssumcd to be CotMant regardless of the oxidation current density chosen, then conclusions are drawn that the incorporated phosphorus is m&k, and that the m&ration rate of it is h&h for a high oxidation current density. The apparent dqraa of m@ration of the inomporatcd phosphorus *ss evaluated as a function of the current density for the anodization. on the assumption that the transport number of tantalum ions was 0.243. INTR0DUcr10N
๐ SIMILAR VOLUMES
## Ahstract -After heating the anodic oxide tilm on tantalum, a constant current or voltage was applied to the specimen in a diluted phosphoric acid solution. and the transient behaviour was examined according to the Frcnkel defect model. Interstitial ions taking part in ionic conduction are captu
It has been shown previously that the kinetics of anodic film growth on Ta, Nb and Zr often depend strongly on the nature of the electrolyte. This work is an attempt to resolve this anomaly and the inconsistencies in the reported structures of the oxide layers. Electron diffraction showed the anodic