Kinetics of oxidation of neutralized glycollic acid by hexachloroiridate(IV)
β Scribed by Kalyan Kali Sen Gupta; Surajit Maiti; Subrata Mandai
- Publisher
- Springer
- Year
- 1984
- Tongue
- English
- Weight
- 300 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0340-4285
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π SIMILAR VOLUMES
Kinetic data for the oxidation of D-glucose by hexachloroiridate(IV) and tetrachloroaurate(II1) are reported. The reactions have been studied spectrophotometrically over a wide range of experimental conditions. The activation parameters have been calculated and mechanisms are suggested.
The kinetics of the reduction of hexachloroiridate(IV) by benzyl alcohol (PhCH 2 OH), some substituted benzyl alcohols (XC 6 H 4 CH 2 OH, where X = NO 2 , Cl and OMe), and benzhydrol (Ph 2 CHOH) to give benzaldehyde, the corresponding substituted benzaldehydes and benzophenone, respectively, were in