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Kinetics and mechanism of sulphurous acid oxidation by hexachloroiridate(IV) in hydrochloric acid

✍ Scribed by Kalyan K. Sen Gupta; Sankar Das; Pratik K. Sen

Publisher
Springer
Year
1987
Tongue
English
Weight
428 KB
Volume
12
Category
Article
ISSN
0340-4285

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Kinetics and mechanism of oxidation of a
Kinetics and mechanism of oxidation of aurate(I) by peroxydisulphate in aqueous hydrochloric acid
✍ R. M. Babshet; G. S. Gokavi πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 132 KB

## Abstract The reaction between Au(I), generated by reaction of thallium(I) with Au(III), and peroxydisulphate was studied in 5 mol dm^βˆ’3^ hydrochloric acid. The reaction proceeds with the formation of an ion‐pair between peroxydisulphate and chloride ion as the Michealis–Menten plot was linear wi