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Kinetics and mechanism of the oxidation of some neutralized α-Hydroxy acids by hexachloroiridate(IV)

✍ Scribed by Kalyan K. Sengupta; Surajit Maiti; Uma Chatterjee; Tapashi Samanta

Publisher
Springer
Year
1982
Tongue
English
Weight
395 KB
Volume
7
Category
Article
ISSN
0340-4285

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Kinetics and mechanism of the oxidation
Kinetics and mechanism of the oxidation of some α-hydroxy acids by 2,2′-bipyridinium chlorochromate
✍ Vinita Kumbhat; Pradeep K. Sharma; Kalyan K. Banerji 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 142 KB

## Abstract The oxidation of glycolic, lactic, malic, and a few substituted mandelic acids by 2,2′‐bipyridinium chlorochromate (BPCC) in dimethylsulphoxide leads to the formation of corresponding oxoacids. The reaction is first order each in BPCC and the hydroxy acids. The reaction is catalyzed by