Kinetics and mechanism of the cerium(1V) oxidation of Cr(II1) complexes of a series of macrocyclic (or pseudomacrocyclic) ligands with L14l-membered intraligand rinqsizes have now been investigated at I = 1.0 Tvf !LiClO.d Temp. 30°C. The complexes of' the formulation Cr(macrocycle)(X)(H20)'3 ''I-whe
Kinetics of oxidation of α-hydroxy acids by chromium(VI) and cerium(IV).
✍ Scribed by P.S. Radhakrishnamurti; T.Ch. Behera
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- French
- Weight
- 101 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0040-4039
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## Abstract The Ce(IV) oxidation of the five‐, six‐, and seven‐membered ring α‐hydroxycycloalkanecarboxylic (C5, C6, and C7) acids to the corresponding cyclic ketones has been studied in acidic perchlorate media. The data may be interpreted in terms of a mechanism which involves fast preequilibrium