Oxidative bisdecarboxylation of α-alkoxymalonic acids with cerium(IV)
✍ Scribed by Robert G. Salomon; Subhas Roy; Mary F. Salomon
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 239 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Ceric ammonium nitrate is an excellent reagent for preparing carboxylic esters from a-alkoxymalonic acids by oxidative bisdecarboxylation.
📜 SIMILAR VOLUMES
Some Part Vill, theoretical considerations in analytical Rigorous calculation of the hydrogen-ion of acids and bases: a correction chemistry concentration A rcccnt note by one of usr gave an erroneous derivation of an equation for the hydrogen-ion concentration of a cnF solution of an acid HA.
The kinetics of the oxidation of n-galactose, D-glucose, o-mannose, D-fructose, L-sorbose, L-arabinose, D-ribose, and rr-xylose with cerium(IV) in perchloric acid were studied. Two complexes were found to form in each case. The first complex forms in a pre-equilibrium reaction during mixing in the s