Partial oxidation of aliphatic side chains with cerium (IV)
โ Scribed by Ludwik Syper
- Publisher
- Elsevier Science
- Year
- 1966
- Tongue
- French
- Weight
- 225 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
IV) bisporphyrinates / Sandwich complexes / Diporphyrins / ฯ Radical-cations and dications / Cerium(III) bisporphyrinate anions Starting from 5-(4-hydroxyphenyl)-10,15,20-tris(4-methylphenyl)porphyrin (2a), the new bis(porphyrinyloxy)alkanes 4a and 4d were synthesized by ether formation with the ฮฑ,ฯ
The kinetics of the oxidation of n-galactose, D-glucose, o-mannose, D-fructose, L-sorbose, L-arabinose, D-ribose, and rr-xylose with cerium(IV) in perchloric acid were studied. Two complexes were found to form in each case. The first complex forms in a pre-equilibrium reaction during mixing in the s