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Kinetics and mechanism of the oxidation ofα-hydroxy acids by benzyltrimethylammonium chlorobromate

✍ Scribed by Anjana; Pradeep K Sharma; Kalyan K Banerji


Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
1999
Tongue
English
Weight
293 KB
Volume
111
Category
Article
ISSN
0253-4134

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Kinetics and mechanism of the oxidation
✍ Deepa Suri; Seema Kothari; Kalyan K. Banerji 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 276 KB 👁 2 views

The oxidation of thioglycolic, thiolactic, and thiomalic acids by benzyltrimethylammonium dichloroiodate (BTMAIC) to the corresponding disulhde dimer, is first-order with respect to each the thioacid and BTMAIC The rates of oxidation were determined at different temperatures and the activation param

Kinetics and mechanism of the oxidation
✍ Vinita Kumbhat; Pradeep K. Sharma; Kalyan K. Banerji 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 142 KB

## Abstract The oxidation of glycolic, lactic, malic, and a few substituted mandelic acids by 2,2′‐bipyridinium chlorochromate (BPCC) in dimethylsulphoxide leads to the formation of corresponding oxoacids. The reaction is first order each in BPCC and the hydroxy acids. The reaction is catalyzed by