Kinetics and mechanism of the oxidation ofα-hydroxy acids by benzyltrimethylammonium chlorobromate
✍ Scribed by Anjana; Pradeep K Sharma; Kalyan K Banerji
- Publisher
- Indian Academy of Sciences,Royal Society of Chemistry
- Year
- 1999
- Tongue
- English
- Weight
- 293 KB
- Volume
- 111
- Category
- Article
- ISSN
- 0253-4134
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The oxidation of thioglycolic, thiolactic, and thiomalic acids by benzyltrimethylammonium dichloroiodate (BTMAIC) to the corresponding disulhde dimer, is first-order with respect to each the thioacid and BTMAIC The rates of oxidation were determined at different temperatures and the activation param
## Abstract The oxidation of glycolic, lactic, malic, and a few substituted mandelic acids by 2,2′‐bipyridinium chlorochromate (BPCC) in dimethylsulphoxide leads to the formation of corresponding oxoacids. The reaction is first order each in BPCC and the hydroxy acids. The reaction is catalyzed by