Kinetics and mechanism of the oxidation of ethylene glycol, 2,3-butanediol and pinacol by hexachloroiridate(IV)
โ Scribed by Kalyan Kali Sen Gupta; Surajit Maiti; Tapashi Samanta; Sanghamitra Nandi; Amalendu Banerjee
- Publisher
- Springer
- Year
- 1982
- Tongue
- English
- Weight
- 534 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0340-4285
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๐ SIMILAR VOLUMES
Kinetic data for the oxidation of D-glucose by hexachloroiridate(IV) and tetrachloroaurate(II1) are reported. The reactions have been studied spectrophotometrically over a wide range of experimental conditions. The activation parameters have been calculated and mechanisms are suggested.
The oxidation of selenium(IV) by permanganate has been studied kinetically in acid, neutral and alkaline media. The reaction exhibits unit-order dependence on selenium(IV) and permanganate in all the three media. Manganese(VI) retards the reaction in alkaline medium. The rate-limiting step is the sa