The kinetics of oxidation of 1,4-Dioxane (Dio) by Diperiodatonickelate (IV) (DPN) in aqueous alkaline medium at a constant ionic strength of 1.5 mol dm Οͺ3 was studied spectrophotometrically. The reaction shows first-order kinetics in [DPN] and less than unit order dependence each in [Dio] and [OH Οͺ
Kinetics and Mechanism of Oxidation of Ethylene Glycol Monoethylether by Diperiodatonickelate(IV) in Alkaline Medium
β Scribed by Jin-Huan Shan; Hai-Ying Wei; Shi-Gang Shen; Han-Wen Sun
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 264 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0256-7660
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## Abstract The kinetics of oxidation of sarcosine by diperiodatocuprate(III) (DPC) was studied with spectrophotometry in a temperature range of 292.2β304.2 K. The reaction between diperiodatocuprate(III) and sarcosine in alkaline medium exhibits 1:1 stoichiometry (DPC:sarcosine). The reaction was