## Abstract The rates of oxidation of phenylthioacetic acid (PTAA) and several substituted phenylthioacetic acids by potassium peroxodiphosphate (PP) in 50% (v/v) aqueous acetic acid have been studied in detail. The rate of oxidation is expressed as An analysis of the dependence of the rate on [H
Kinetics and mechanism of oxidation of S-phenylthioacetic acids by Ce(IV)
โ Scribed by Rajagopala Gurumurthy; Mannathusamy Gopalakhrishnan; Kulathu Iyer Sathiyanarayanan
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- French
- Weight
- 409 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0040-4020
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The kinetics of the oxidation of certain biologically important pyrimidine bases [Uracil, Thymine, and 6-Methyluracil) by Ce( IV) in aqueous H,SO, has been investigated. A first-order dependence of rate each on ICe(lV)], Ipyrimidinel, and an inverse first-order dependence on I ki ,SO,, I has been ob
The oxidation of selenium(IV) by permanganate has been studied kinetically in acid, neutral and alkaline media. The reaction exhibits unit-order dependence on selenium(IV) and permanganate in all the three media. Manganese(VI) retards the reaction in alkaline medium. The rate-limiting step is the sa