Kinetics and mechanism of Ru(III) catalyzed oxidation of Se(IV) by Ce(IV)
β Scribed by D.S.A. Dikshitulu; P. Vani; V. Hanumantna Rao
- Publisher
- Elsevier Science
- Year
- 1981
- Weight
- 241 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0020-1650
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The kinetics of the oxidation of certain biologically important pyrimidine bases [Uracil, Thymine, and 6-Methyluracil) by Ce( IV) in aqueous H,SO, has been investigated. A first-order dependence of rate each on ICe(lV)], Ipyrimidinel, and an inverse first-order dependence on I ki ,SO,, I has been ob
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The kinetics of oxidation of ethanol by cerium(1V) in presence of ruthenium(II1) (in the order of mol dm-3) in aqueous sulfuric acid media have been followed at different temperatures (25-40Β°C). The rate of disappearance of cerium(1V) in the title reaction increases sharply with increasing [CzH50H]