𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetics of oxidation of certain pyrimidines by Ce(IV)

✍ Scribed by S. Lakshmi; R. Renganathan

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
381 KB
Volume
28
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis

The kinetics of the oxidation of certain biologically important pyrimidine bases [Uracil, Thymine, and 6-Methyluracil) by Ce( IV) in aqueous H,SO, has been investigated. A first-order dependence of rate each on ICe(lV)], Ipyrimidinel, and an inverse first-order dependence on I ki ,SO,, I has been observed Rate and activation parameters for the oxidation of these pyrimidines have been computed A suitable rate law and a mechanism consistent with the kinetic observations and product analysis have been proposed. 0 IY96 lohn Wiley &Sons. Inc

πŸ“œ SIMILAR VOLUMES

Kinetic Study of the Oxidation of Dimeth
Kinetic Study of the Oxidation of Dimethylsulfoxide by Cerium(IV) in Perchloric Acid Media
✍ F. Mata-PΓ©rez; M. L. MuΓ±oz; M. P. Álvarez πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 German βš– 87 KB πŸ‘ 2 views

The kinetics of the oxidation of dimethylsulfoxide by Cerium(IV) in perchloric acid has been investigated spectrophotometrically. The water role has been elucidates by using acidity criteria. A tentative mechanism consistent with the kinetics is dis- ## Kinetische Untersuchung der Oxidation von Dim