𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Homogeneous and Biphasic Nickel-Catalyzed Isomerization of Allylic Alcohols

✍ Scribed by Hervé Bricout; Eric Monflier; Jean-François Carpentier; André Mortreux

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
215 KB
Volume
1998
Category
Article
ISSN
1434-1948

No coin nor oath required. For personal study only.

✦ Synopsis

The nickel-catalyzed isomerization of geraniol and prenol in roacetic acid combination. Catalyst deactivation occurs in the course of the reaction owing to coordination of the formed homogeneous and two-phase systems has been investigated. The best results in terms of activity and selectivity have been aldehyde group to the nickel species or as a result of protonolysis of hydrido-or (π-allyl)nickel complexes. obtained in homogeneous systems with a bis(cycloocta-1,5diene)nickel(0)/1,4-bis(diphenylphosphanyl)butane/trifluo-

📜 SIMILAR VOLUMES

Iridium-Catalyzed Asymmetric Isomerizati
Iridium-Catalyzed Asymmetric Isomerization of Primary Allylic Alcohols
✍ Luca Mantilli; David Gérard; Sonya Torche; Céline Besnard; Clément Mazet 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 374 KB 👁 1 views

## Abstract **Nothing to sm(Ir)k at**: Under appropriate reaction conditions, iridium hydride catalysts promote the isomerization of primary allylic alcohols. The best catalysts, like (__R__)‐**1** (P green, O red, N blue, Ir yellow), deliver the desired chiral aldehydes with excellent enantioselec

Palladium-Catalyzed Isomerization of exo
Palladium-Catalyzed Isomerization of exo-Methylenic Allylic Alcohols
✍ Paul S. Fordred; D. Gangani Niyadurupola; Richard Wisedale; Steven D. Bull 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 209 KB 👁 1 views

## Abstract Treatment of allylic alcohols containing a 1,1‐disubstituted alkene with a palladium catalyst and hydrogen gas (1 bar) results in facile isomerization to their corresponding trisubstituted (__E__)‐allylic alcohols, along with small amounts of the corresponding hydrogenated products.

Iridium-Catalyzed Asymmetric Isomerizati
Iridium-Catalyzed Asymmetric Isomerization of Primary Allylic Alcohols
✍ Luca Mantilli; David Gérard; Sonya Torche; Céline Besnard; Clément Mazet 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 373 KB 👁 1 views

## Abstract **Unter sehr milden Reaktionsbedingungen** vermitteln Iridiumhydridkatalysatoren die Isomerisierung primärer Allylalkohole. Die besten Katalysatoren, darunter (__R__)‐**1**, liefern die gewünschten chiralen Aldehyde mit ausgezeichneten Enantioselektivitäten und in guten Ausbeuten. Auf d