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Palladium-Catalyzed Isomerization of exo-Methylenic Allylic Alcohols

✍ Scribed by Paul S. Fordred; D. Gangani Niyadurupola; Richard Wisedale; Steven D. Bull

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
209 KB
Volume
351
Category
Article
ISSN
1615-4150

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✦ Synopsis

Abstract

Treatment of allylic alcohols containing a 1,1‐disubstituted alkene with a palladium catalyst and hydrogen gas (1 bar) results in facile isomerization to their corresponding trisubstituted (E)‐allylic alcohols, along with small amounts of the corresponding hydrogenated products.

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