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Iridium-Catalyzed Asymmetric Isomerization of Primary Allylic Alcohols

✍ Scribed by Luca Mantilli; David Gérard; Sonya Torche; Céline Besnard; Clément Mazet

Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 374 KB
Volume: 48
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200901863

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✦ Synopsis

Abstract

Nothing to sm(Ir)k at: Under appropriate reaction conditions, iridium hydride catalysts promote the isomerization of primary allylic alcohols. The best catalysts, like (R)‐1 (P green, O red, N blue, Ir yellow), deliver the desired chiral aldehydes with excellent enantioselectivity and good yields. Mechanistic hypotheses have been developed on the basis of preliminary investigations.magnified image

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