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ChemInform Abstract: Iridium-Catalyzed Asymmetric Isomerization of Primary Allylic Alcohols.

✍ Scribed by Luca Mantilli; David Gerard; Sonya Torche; Celine Besnard; Clement Mazet

Publisher
John Wiley and Sons
Year
2009
Weight
37 KB
Volume
40
Category
Article
ISSN
0931-7597

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Iridium-Catalyzed Asymmetric Isomerizati
Iridium-Catalyzed Asymmetric Isomerization of Primary Allylic Alcohols
✍ Luca Mantilli; David Gérard; Sonya Torche; Céline Besnard; Clément Mazet 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 374 KB 👁 1 views

## Abstract **Nothing to sm(Ir)k at**: Under appropriate reaction conditions, iridium hydride catalysts promote the isomerization of primary allylic alcohols. The best catalysts, like (__R__)‐**1** (P green, O red, N blue, Ir yellow), deliver the desired chiral aldehydes with excellent enantioselec

Iridium-Catalyzed Asymmetric Isomerizati
Iridium-Catalyzed Asymmetric Isomerization of Primary Allylic Alcohols
✍ Luca Mantilli; David Gérard; Sonya Torche; Céline Besnard; Clément Mazet 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 373 KB 👁 1 views

## Abstract **Unter sehr milden Reaktionsbedingungen** vermitteln Iridiumhydridkatalysatoren die Isomerisierung primärer Allylalkohole. Die besten Katalysatoren, darunter (__R__)‐**1**, liefern die gewünschten chiralen Aldehyde mit ausgezeichneten Enantioselektivitäten und in guten Ausbeuten. Auf d