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Iridium-Catalyzed Asymmetric Isomerization of Primary Allylic Alcohols

✍ Scribed by Luca Mantilli; David Gérard; Sonya Torche; Céline Besnard; Clément Mazet

Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 373 KB
Volume: 121
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.200901863

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✦ Synopsis

Abstract

Unter sehr milden Reaktionsbedingungen vermitteln Iridiumhydridkatalysatoren die Isomerisierung primärer Allylalkohole. Die besten Katalysatoren, darunter (R)‐1, liefern die gewünschten chiralen Aldehyde mit ausgezeichneten Enantioselektivitäten und in guten Ausbeuten. Auf der Grundlage von ersten Untersuchungen wurde ein mechanistisches Modell entwickelt.magnified image

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