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ChemInform Abstract: Palladium-Catalyzed Isomerization of exo-Methylenic Allylic Alcohols.

✍ Scribed by Paul S. Fordred; D. Gangani Niyadurupola; Richard Wisedale; Steven D. Bull

Publisher
John Wiley and Sons
Year
2010
Weight
45 KB
Volume
41
Category
Article
ISSN
0931-7597

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Palladium-Catalyzed Isomerization of exo
Palladium-Catalyzed Isomerization of exo-Methylenic Allylic Alcohols
✍ Paulβ€…S. Fordred; D. Gangani Niyadurupola; Richard Wisedale; Stevenβ€…D. Bull πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 209 KB πŸ‘ 1 views

## Abstract Treatment of allylic alcohols containing a 1,1‐disubstituted alkene with a palladium catalyst and hydrogen gas (1β€…bar) results in facile isomerization to their corresponding trisubstituted (__E__)‐allylic alcohols, along with small amounts of the corresponding hydrogenated products.