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Di-μ-ethoxy-bis­[diethoxy(8-quinolinato)­titanium(IV)]

✍ Scribed by Amini, Mostafa M. ;Mirzaee, Mehdi ;Ng, Seik Weng


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
190 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis


The hydroxyquinolinate group chelates to the Ti atom in the centrosymmetric title compound, [Ti 2 (C 9 H 6 NO) 2 (C 2 H 5 O) 6 ]. Two of the four ethoxy groups function as bridges, and the geometry of the six-coordinate Ti atom is that of an octahedron.


📜 SIMILAR VOLUMES


Studies of Organometallic Compounds XVI.
✍ Helen Stoeckli-Evans 📂 Article 📅 1975 🏛 John Wiley and Sons 🌐 German ⚖ 351 KB

The crystal structure of di-pcthoxy-bis(dibenzy1ethox y-titaniurn(IV)), r(EtO),'Ci-(CHgPh)B]B, has been determined from analysis of photographic X-ray data. Thc crystal system is monoclinic, a = 7.93(2), b = 15.99(2), c = 13.40(2) A, p = 92.7(3)", space group PZ,/c. Tho molecule is a dimcr situated

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Single-crystal X-ray study T = 163 K Mean '(C±C) = 0.004 A Ê R factor = 0.032 wR factor = 0.082 Data-to-parameter ratio = 19.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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cis-Bis(8-hydroxy­quinolinato-κ2N,O)­di­
✍ Linden, Anthony ;Basu Baul, Tushar S. ;Mizar, Archana 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 186 KB

The coordination geometry at the Sn atom in the title compound, [Sn(C 6 H 5 ) 2 (C 9 H 6 NO) 2 ], is distorted cis-octahedral, in which the two phenyl ligands are cis to one another and trans to the N atoms of the oxinate ligands. This arrangement brings the oxinate O atoms into a trans relationship